Soybean lipoxygenase-I was incubated with 18O2-13-S-hydroperoxy 9-cis, 11-trans octadecadienoic-acid. It was shown, by18O content, degree of racemisation and of isomerisation that the enzyme catalysed the exchange of molecular oxygen with the oxygen atoms of the OOH group which is stereoselectively retained in the 13(S) conjiguraton after exchange.
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Matthew et al. (1983) studied this question.
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