Controlling the Scattering Length of Ultracold Dipolar Molecules

By applying a circularly polarized and slightly blue-detuned microwave field with respect to the first excited rotational state of a dipolar molecule, one can engineer a long-range, shallow potential well in the entrance channel of the two colliding partners. As the applied microwave ac field is increased, the long-range well becomes deeper and can support a certain number of bound states, which in turn bring the value of the molecule-molecule scattering length from a large negative value to a large positive one. We adopt an adimensional approach where the molecules are described by a rescaled rotational constant Bover ˜=B/s₄_₃ where s₄_₃ is a characteristic dipolar energy. We found that molecules with Bover ˜>10^8 are immune to any quenching losses when a sufficient ac field is applied, the ratio elastic to quenching processes can reach values above 10^3, and that the value and sign of the scattering length can be tuned. The ability to control the molecular scattering length opens the door for a rich, strongly correlated, many-body physics for ultracold molecules, similar to that for ultracold atoms.