Synapse
⌘+K
Synapse
PulseExploreClubsResearchersJournals
Instagram
HomeClubsExplore
June 6, 2026Journal of the American Chemical SocietyOpen Access

Kinetics vs Thermodynamics: Engineering Photoredox Reactivity from an Upper Excited State of Fe II

View Full Paper
Ask AI
Bookmark
Share

Authors

AGAtanu GhoshBPBjörn PfundJYJonathan T. Yarranton

Discussion

Loading...

Member takes

Overview

Randomized trial explores electron transfer kinetics in Fe II compounds, indicating potential for energy conversion applications.

Key Points

  • This research investigates how to optimize electron transfer from an excited state of Fe II to improve energy conversion.
  • Conducted variable-temperature transient absorption studies to analyze excited-state dynamics.
  • Estimated excited-state redox potential based on findings related to ground-state recovery processes.
  • Examined competing thermodynamic and kinetic pathways for electron transfer.
  • Identified the recovery process near the Marcus barrierless regime, facilitating electron transfer.
  • Determined the excited-state redox potential, aiding in effective electron transfer optimization.
  • Opened new avenues for using earth-abundant transition metal chromophores in light-to-chemical energy conversion.

Cite This Study

Ghosh et al. (2026) studied this question.

synapsesocial.com/papers/6a23bb4471a5da9775e76c71https://doi.org/10.1021/jacs.6c02681
View Full Paper
Ask AI
Bookmark
Share

Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

  1. 1Cage escape governs photoredox reaction rates and quantum yields2024 · 43 citations
  2. 2Nature of Anti‐Dissipative High‐Energy Excited States in Quaterpyridine‐Bridged Ruthenium Complexes2025 · 12 citations
  3. 3Photo-Induced Spin-State Conversion in Solvated Transition Metal Complexes Probed via Time-Resolved Soft X-ray Spectroscopy2010
  4. 4The Connection between NHC Ligand Count and Photophysical Properties in Fe(II) Photosensitizers: An Experimental Study2017 · 93 citations
  5. 5Nanosecond Intra-Ionic Chloride Photo-Oxidation2023 · 15 citations