Metal Sources of Zn–Pb and Bauxite Deposits in the Sichuan–Yunnan–Guizhou Region: Constraints from Pb Isotopes and Zn/Cd Ratios of Basement and Cover Strata

Critical metals such as gallium and germanium are strategic mineral resources widely used in advanced technology, including semiconductors and solar cells. These metals are recovered as by-products from the processing of Zn–Pb and bauxite ores. In China, the Sichuan–Yunnan–Guizhou (SYG) region is abundant in Zn–Pb and bauxite ore deposits, such as the Huize Zn–Pb–Ge deposit and the Wuchuan–Zheng’an–Daozhen (WZD) area Al–Ga deposit. Although previous studies have proposed models to explain the enrichment mechanisms of critical metals in this area, the metal sources of these deposits remain controversial. In this study, samples were collected from the Paleoproterozoic Kunyang Group to the Permian Emeishan basalts, and the metal sources of these deposits were traced by comparing the Pb isotopic ratios and Zn/Cd ratios of potential source rocks and deposits. The findings indicate: (1) The Pb isotopic compositions of most samples are relatively homogeneous, but certain differences exist among strata from different geological periods. (2) The metal sources of the Yunnan and Guizhou bauxite may both have been controlled by the underlying carbonate rocks, but the specific source horizons differ significantly between the two regions. (3) Based on the Pb isotopic compositions of regional strata and Zn–Pb deposits, it appears that the regional basement and sedimentary cover likely contributed significantly to the ore-forming metals, whereas the Emeishan basalts may have played a relatively minor role. However, due to the complex lithology and substantial thickness of the basement and cover strata in the SYG region, there may be issues of sampling inadequacy. Nonetheless, this study provides important foundational data and insights for tracing the metal sources of deposits in this region using Pb isotopes and Zn/Cd ratios.