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• A high power factor value of 207.8 μW m −1 K −2 is achieved in 0.1 wt% GQDs-incorporated PEDOT:PSS films. • The incorporation of trace amounts of GQDs into the PSS and PEDOT matrix enhances the π-π conjugation. • The solvent-free approach simplifies the fabrication of high-performance thermoelectric films. • The fabricated devices achieve an excellent output power density of 54.6 μW cm −2 . Conductive polymers, particularly poly(3,4-ethylenedioxythiophene):(styrene sulfonate) (PEDOT:PSS), are gaining significant attention in flexible thermoelectrics due to their excellent flexibility, low thermal conductivity, and structural stability. However, the electrical conductivity of pristine PEDOT:PSS (below 1 S cm −1 ) limits its power factor. Although polar solvent doping can enhance electrical conductivity, such methods often require complex acid-based post-treatments, compromising material stability and safety. Here, we report highly conductive graphene quantum dot (GQDs)-incorporated PEDOT:PSS films, fabricated via a solvent-free process. The incorporation of trace amounts of GQDs into the PSS and PEDOT matrix enhances the π-π conjugation within the PEDOT matrix, achieving a electrical conductivity of 3027 S cm −1 and a power factor of up to 207.8 μW m −1 K −2 at room temperature. The solvent-free process preserves film flexibility, making them ideal for flexible thermoelectric devices. These findings present a scalable strategy to enhance the performance of organic thermoelectric materials.
Wu et al. (Wed,) studied this question.