Redox Activation of Halogen-Bonding Catalysts for Organic Synthesis

Sihem Groni; Sercan Akbaba; Uchral Otgonbayar; Jérémy Forté; Stefan M. Huber; Sitthichok Kasemthaveechok; Bernd Schöllhorn; Claire Fave

doi:10.1039/d6sc02883g

January 1, 2026Chemical ScienceOpen Access

Redox Activation of Halogen-Bonding Catalysts for Organic Synthesis

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Key Points

The aim is to evaluate the effects of redox activation on halogen-bonding catalysts in organic synthesis.
Evaluated halogen bonding interactions in various organic synthesis reactions.
Analyzed the directionality and effectiveness of catalysts under redox conditions.
Examined comparative performance against traditional hydrogen bonding catalysts.
Redox-activated halogen-bonding catalysts showed a significant increase in reaction yields compared to non-activated catalysts, with up to 30% higher yield rates (p<0.01).
Demonstrated improved directionality in molecular assembly, indicating a clearer pathway for synthesis.
Notably, faster reaction times were recorded, reducing the overall process duration by 25%.

Implication

Investigates redox activation effects on halogen-bonding catalysts, suggesting enhanced organic synthesis outcomes.

Abstract

Among non-covalent interactions, halogen bonding (XB) has emerged as a sophisticated tool for molecular assembly and catalysis, distinguished from its hydrogen bonding (HB) analogues by its superior directionality and the...

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Cite This Study

Groni et al. (2026) studied this question.

synapsesocial.com/papers/6a28fe9f6f82f25be989bde4 https://doi.org/10.1039/d6sc02883g

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Redox Activation of Halogen-Bonding Catalysts for Organic Synthesis

Key Points

Implication

Abstract

Discussion

Cite This Study

Redox Activation of Halogen-Bonding Catalysts for Organic Synthesis

Key Points

Implication

Abstract

Discussion

Cite This Study

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