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June 10, 2026ACS Applied Energy Materials

A Hybrid Solid Electrolyte Enabled by Dual MOFs and Ionic Liquids for Stable Solid-State Lithium Batteries

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Authors

LJLi JWannan Medical CollegeGYGenxi YuChangzhou Institute of TechnologyLJLi JWannan Medical College

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Implication

Randomized trial demonstrates enhanced stability and conductivity in lithium batteries using composite polymer electrolytes, suggesting a viable energy storage solution.

Key Points

  • To develop a hybrid solid electrolyte combining metal-organic frameworks and ionic liquids for improved performance in lithium batteries.
  • Synthesis of zirconium-based metal-organic frameworks (MOF-801 and MOF-808) and formation of composite MOF-801@808 filler.
  • Incorporation of lithium salt-loaded ionic liquids into the composite MOF and poly(ethylene oxide) matrix to create a composite polymer electrolyte.
  • Testing the ionic conductivity, electrochemical stability, and cycling performance of the composite polymer electrolyte in lithium cells.
  • Achieved a room-temperature ionic conductivity of approximately 1.67 × 10 −4 S·cm −1 and an electrochemical stability window of ~5.22 V.
  • Observed a Li + transference number of ~0.31 and maintained stable operation for over 600 h in Li||CPE||Li symmetric cells.
  • In Li||CPE-4||LFP full cells, an initial discharge capacity of 143 mAh g −1 was achieved at 0.2C, retaining over 130 mAh g −1 after 40 cycles with >98% Coulombic efficiency.

Cite This Study

J et al. (2026) studied this question.

synapsesocial.com/papers/6a29012e6f82f25be989d929https://doi.org/10.1021/acsaem.6c00493
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