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June 8, 2026The Journal of Physical Chemistry A

Photoelectron Imaging Spectroscopy and Density Functional Theory Calculations of Al-Doped Silver Cluster Anions: Ag n Al – ( n = 4–17)

Rin Nomi Yuta Suzuki Yuta Ushiki Akira Terasaki T. Horio

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Key Points

This study aims to investigate the electronic structure of aluminum-doped silver cluster anions using photoelectron imaging and computational methods.
Conducted photoelectron imaging spectroscopy on Ag_nAl^- clusters where n ranges from 4 to 17.
Employed density functional theory calculations to analyze the electronic configurations.
Compared experimental data with predictions from the spherical jellium model.
Electronic structure revealed unexpected positioning of 2S-like orbitals within the 1D-like orbital manifold.
Findings indicate deviations from the spherical jellium model, challenging existing theoretical predictions.

Implication

This randomized trial analyzes the electronic structure of Al-doped silver cluster anions, suggesting deviations from the spherical jellium model.

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Cite This Study

Nomi et al. (2026) studied this question.

synapsesocial.com/papers/6a2a512e80c8f91e7f39d803 https://doi.org/10.1021/acs.jpca.6c01281

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