Unlocking Superionic Conduction by Modulating Electrostatic Interactions in a Zirconium-Based Trigonal Halide Solid Electrolyte

Joohyeon Noh; Seungju Yu; Sunyoung Lee; Wonju Kim; Kyungho Yoon; Sangwook Han; Junhyuk Song; Kyungbae Oh; Chanwoong Park; Daero Won; Geunji Choi; Kangtaek Lee; Kisuk Kang

doi:10.1039/d6eb00070c

January 1, 2026EES batteries.Open Access

Unlocking Superionic Conduction by Modulating Electrostatic Interactions in a Zirconium-Based Trigonal Halide Solid Electrolyte

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Key Points

This research aims to enhance ionic conduction in zirconium-based halides by adjusting electrostatic interactions.
Analyzed the conductivity of Li2ZrCl6 by manipulating electrostatic properties.
Conducted experiments to evaluate ionic transport mechanisms.
Compared the performance of zirconium-based halides with other solid electrolytes.
Achieved a significant increase in ionic conductivity under specific electrostatic conditions.
Demonstrated that structural modulation improves the superionic behavior of Li2ZrCl6.
Found a notable compatibility with cathode materials, enhancing battery potential.

Implication

Investigates superionic conduction in solid electrolytes, suggesting enhanced battery performance.

Abstract

Halide solid electrolytes have recently emerged as promising candidates for solid-state batteries, combining high ionic conductivity, favorable cathode compatibility, and mechanical softness. Among them, the zirconium-based halide Li 2 ZrCl 6 has attracted...

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Cite This Study

Noh et al. (2026) studied this question.

synapsesocial.com/papers/6a2a51d780c8f91e7f39dfaf https://doi.org/10.1039/d6eb00070c

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Unlocking Superionic Conduction by Modulating Electrostatic Interactions in a Zirconium-Based Trigonal Halide Solid Electrolyte

Key Points

Implication

Abstract

Discussion

Cite This Study

Unlocking Superionic Conduction by Modulating Electrostatic Interactions in a Zirconium-Based Trigonal Halide Solid Electrolyte

Key Points

Implication

Abstract

Discussion

Cite This Study

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