Palladium-catalyzed Synthesis of S-Aryl Thiocarbamate via Desulfurative C-S Cross-coupling Reaction of Dithiocarbamates

Rahul Mondal; Manas Mondal; Amit Kumar Saha

doi:10.1039/d6ob00331a

January 1, 2026Organic & Biomolecular Chemistry

Palladium-catalyzed Synthesis of S-Aryl Thiocarbamate via Desulfurative C-S Cross-coupling Reaction of Dithiocarbamates

View Full Paper

Ask AI

Bookmark

Share

Key Points

To develop a new method for synthesizing S-aryl thiocarbamate through desulfurative cross-coupling.
Utilized Pd(II) catalyst and Cu(II) oxidant for the reaction.
Combined dithiocarbamate esters with arylsilanes in a cross-coupling process.
Successfully synthesized S-aryl thiocarbamate with high yields.
Demonstrated the efficiency of desulfurative C-S cross-coupling reactions.

Implication

Demonstrates a new synthesis method for S-aryl thiocarbamate, suggesting improved efficiency.

Abstract

A new protocol for synthesizing S-aryl thiocarbamate has been demonstrated here by the desulfurative C-S cross coupling of dithiocarbamate esters with arylsilanes in presence of Pd(II)-catalyst and Cu(II)-oxidant. A series...

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Mondal et al. (2026) studied this question.

synapsesocial.com/papers/6a2a52ae80c8f91e7f39e8f3 https://doi.org/10.1039/d6ob00331a

View Full Paper

Ask AI

Bookmark

Share

Palladium-catalyzed Synthesis of S-Aryl Thiocarbamate via Desulfurative C-S Cross-coupling Reaction of Dithiocarbamates

Key Points

Implication

Abstract

Discussion

Cite This Study

Palladium-catalyzed Synthesis of S-Aryl Thiocarbamate via Desulfurative C-S Cross-coupling Reaction of Dithiocarbamates

Key Points

Implication

Abstract

Discussion

Cite This Study

Keep reading

Keep reading