Research demonstrates enhanced emission and robust chirality in a macrocycle, suggesting implications for synthesis.
positions of the biaryl subunits enhance structural rigidity, resulting in its robust chirality and enhanced emission in its π-extended derivatives. In addition, methyl substitution provides synthetic advantages by shortening the bond-cleavage step and enabling regioselective C-H borylation.
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Kambara et al. (2026) studied this question.
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