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Research Paper | Synapse

June 14, 2026Dalton Transactions0 citations

Light-Responsive Spin-Crossover Iron(II) Complexes with Azo-Pyridyl-Benzimidazole Ligands for Molecular Thin Films

OČOliver Čierny AŠAlexandra ŠagátováSlovak University of Technology in Bratislava JOJakub OrvošSlovak University of Technology in Bratislava

Key Points

This study aims to develop and examine new iron(II) spin-crossover complexes using azo-functionalized ligands.
Synthesis of three new iron(II) spin-crossover complexes with structural characterization.
Utilization of azo-functionalized ligands for enhanced properties.
Investigation of multifunctional properties related to molecular thin films.
Identified three new iron(II) spin-crossover complexes with distinct properties.
Demonstrated the practical applicability of these complexes in molecular thin films.
Reported significant structural features and interaction profiles of the complexes.

Abstract

We report the synthesis, structural characterization, and multifunctional properties of three new iron (II) spin-crossover (SCO) complexes based on the azo-functionalized ligand 2-4-trans-phenyldiazenyl-pyridine-2-yl-1H-benzimidazole (L): Fe (L) 3 (ClO4) 2·C3H6O (1), (Fe (L) 3 (CF3SO3) 2 (2) and Fe (L) 3 (BF4) 2·C6H14O (3). . . .

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Cite This Study

Čierny et al. (Thu,) studied this question.

synapsesocial.com/papers/6a2e45adb1cc60ccdea8ab0f https://doi.org/https://doi.org/10.1039/d6dt00668j