Examines oxidation chemistry in phosphine-substituted biomimics, suggesting enhanced activity.
Ferrocene–dichalcogenolate-bridged complexes, [Fe2(CO)6{μ-E(η5-C5H4)Fe(η5-C5H4)E)}] (E = S, Se), are [FeFe]-hydrogenase biomimics, in which the two redox-active centres lie in close proximity. Here we report the syntheses and electrochemical studies of phosphine-substituted...
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Orton et al. (2026) studied this question.
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