Report on the synthesis and electrochemical properties of palladium(IV)-containing hexatungstate for catalytic hydrogenation.
We report on the synthesis of the palladium(IV)-containing hexatungstate [PdIVW₆O₂₄]⁸⁻ (PdW₆) with a central 6-coordinated PdIV ion, which is surrounded by a ring of six edge-shared WO₆ octahedra. The sodium salt of PdW6 was structurally characterized in the solid state by multiple techniques, and the solution redox chemistry was investigated by electrochemistry. The catalytic hydrogenation of o-xylene using supported PdW6 as a precatalyst was also studied.
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Kulashri et al. (2026) studied this question.
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