Corrosion-Stage Diagnosis of Reclaimed-Water Cast Iron Pipelines Based on Corrosion Acceleration for Sustainable Urban Water Infrastructure

A 700 m pilot-scale cast iron pipeline reactor was operated for 120 days to investigate corrosion-stage evolution under reclaimed-water conveyance conditions. Sampling points were arranged at 50, 250, 450, and 650 m, and water-quality monitoring, coupon weight-loss tests, scanning electron microscopy (SEM), and high-throughput 16S rRNA sequencing were combined to characterize corrosion-rate variation, corrosion-product morphology, and microbial community succession. During transport, NH4+ generally decreased while NO3− increased, indicating nitrification-related nitrogen transformation under aerobic conditions; meanwhile, PO43− declined and DOC fluctuated, reflecting coupled physicochemical and biological processes. SEM observations showed a transition from loose porous deposits to relatively compact layered corrosion products, followed by local deterioration and renewed porous structures in the later period. The corrosion rate followed an increase–decrease–re-increase pattern rather than a monotonic trend. Therefore, corrosion acceleration (CA = dc/dt) was introduced as an auxiliary diagnostic indicator to identify whether corrosion activity was increasing, decreasing, or temporarily stabilizing. Microbial community analysis showed stage-associated variation in biofilm and nitrogen-transformation-related taxa, supporting the interpretation that corrosion evolution was jointly affected by water-quality change, corrosion-product development, and microbial succession. Overall, the combined interpretation of corrosion rate, CA, water quality, SEM morphology, and microbial succession provides a more informative basis for diagnosing corrosion-stage transitions in reclaimed-water cast iron pipelines. From a sustainability perspective, this diagnostic framework can support long-term operation, maintenance planning, and risk monitoring of urban reclaimed-water distribution infrastructure, thereby improving pipeline durability, reducing leakage and maintenance risks, and enhancing the reliability of reclaimed-water reuse systems.