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Complexes in disguise: Homoleptic [Ln(AlMe4)3] (Ln=Y, Lu) complexes are effectively masked [LnMe3]n species, which are produced reversibly upon equimolar addition of a Lewis base to the former. Compounds [LnMe3]n are thermally stable and readily form peralkylated heterobimetallic complexes with alkylaluminum, -gallium, and -magnesium reagents (see scheme). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z463109_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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Dietrich et al. (2005) studied this question.
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