Longitudinal Variations in Inorganic Pollutants and DOM in Rivers Affected by Treated Acid Mine Drainage: A Case Study of Four Closed Coal Mines in Northern Sichuan, China

The environmental impacts of treated acid mine drainage on receiving river systems remain insufficiently understood. This study investigated four typical closed coal mines in northern Sichuan Province, China, by analyzing heavy metals, sulfate, pH, UV-Vis spectroscopy, and dissolved organic matter (DOM) characteristics at 24 sampling sites along the receiving reaches. Parallel factor analysis (PARAFAC) and two-dimensional correlation spectroscopy (2D-COS) were employed to examine the longitudinal response sequence of DOM components. Results showed that pollutant concentrations generally increased immediately after the inflow of treated acid mine drainage and then progressively attenuated downstream, although the dominant pollution factors varied significantly among the reaches. DOM composition exhibited spatial heterogeneity, with protein-like components dominating three reaches and humic-like components prevailing in one reach. Based on the co-variation characteristics of DOM and heavy metals along the river course, four response patterns were identified: rapid-recovery, slow-recovery, disturbance–oscillation recovery, and delayed-recovery patterns. The 2D-COS analysis validated the rationality of these four patterns and revealed differences in the sensitivity of various DOM components to longitudinal disturbances. This study provides a scientific basis for the environmental impact assessment of mine water from remediated closed coal mines.