Generalized Diffusion Theory for Radiative Transfer in Fully Anisotropic Scattering Media

A generalized anisotropic‐diffusion framework is developed for transport problems in media described by a tensorial scattering coefficient and a scalar Henyey–Greenstein asymmetry factor. In this regime the classical similarity relation between scattering and transport parameters fails, and each principal diffusion coefficient depends on all components of the microscopic scattering rate. Explicit expressions are derived for the direction‐averaged mean free path, the diagonal elements of the diffusion tensor, and boundary condition lengths via rapidly convergent spherical‐harmonics expansions, along with open‐source implementations. The resulting predictions are validated against anisotropic Monte Carlo simulations, showing excellent agreement across broad ranges of structural anisotropy and phase‐function asymmetry factors. The theory provides a compact, general route connecting microscopic anisotropic scattering to macroscopic diffusion coefficients and boundary conditions in bounded geometries.