Hydrogen-Bonded Ammonium Dinitramide/Dibenzo-[18]-Crown-6 Cocrystal with Low Hygroscopicity and Reduced Sensitivity

Ming-Chieh Lin; Neng-Chang Li; Yu-Ren Feng; Shih-Tsung Ke; Mohamed Gamal Mohamed; Ahmed A. K. Mohammed; Shiao‐Wei Kuo

doi:10.1039/d6ce00394j

January 1, 2026CrystEngComm

Hydrogen-Bonded Ammonium Dinitramide/Dibenzo-[18]-Crown-6 Cocrystal with Low Hygroscopicity and Reduced Sensitivity

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Key Points

This research aims to develop a cocrystal of ammonium dinitramide and dibenzo-[18]-crown-6 to enhance stability and reduce sensitivity.
Utilized dibenzo-[18]-crown-6 to form a cocrystal with ammonium dinitramide.
Conducted solvent evaporation under controlled temperature and humidity conditions.
Analyzed the cocrystal using single-crystal X-ray diffraction.
The cocrystal exhibited significantly lower hygroscopicity compared to pure ammonium dinitramide.
Characterization confirmed the successful formation of the cocrystal via X-ray analysis.
This new cocrystal formulation showcases enhanced stability for potential applications.

Implication

Demonstrates reduced hygroscopicity in cocrystal, indicating improved stability for applications.

Abstract

Dibenzo-[18]-crown-6 (DB18C6) was used to form a novel cocrystal with ammonium dinitramide (ADN) via solvent evaporation under controlled temperature and humidity conditions to accelerate cocrystallization and reduce hygroscopicity. Single-crystal X-ray...

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Cite This Study

Lin et al. (2026) studied this question.

synapsesocial.com/papers/6a323d23d50b63ecad206fd2 https://doi.org/10.1039/d6ce00394j

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Hydrogen-Bonded Ammonium Dinitramide/Dibenzo-[18]-Crown-6 Cocrystal with Low Hygroscopicity and Reduced Sensitivity

Key Points

Implication

Abstract

Discussion

Cite This Study

Hydrogen-Bonded Ammonium Dinitramide/Dibenzo-[18]-Crown-6 Cocrystal with Low Hygroscopicity and Reduced Sensitivity

Key Points

Implication

Abstract

Discussion

Cite This Study

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