Optimal three-dimensional [Ag ₄ P ₂ S ₆ ]-framework assembly directed by a threefold roto-inversion axis for enhanced birefringence

MF Zhang; C Hu; Jiang‐Gao Mao

doi:10.1039/d6qi00873a

January 1, 2026Inorganic Chemistry Frontiers

Optimal three-dimensional [Ag ₄ P ₂ S ₆ ]-framework assembly directed by a threefold roto-inversion axis for enhanced birefringence

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Key Points

This research focuses on improving the properties of γ-Ag4P2S6 crystals through symmetry engineering.
Engineered γ-Ag4P2S6 crystals using a threefold roto-inversion axis.
Evaluated birefringence, thermal stability, and infrared transmission ranges.
Demonstrated large birefringence in the γ-Ag4P2S6 crystal.
Achieved high thermal stability exceeding 750 °C.
Showed effective infrared transmission from 0.4 to 18.2 μm.

Implication

Reveals high birefringence and thermal stability in engineered γ-Ag4P2S6 crystals, implying promising optical applications.

Abstract

A symmetry-engineered γ-Ag 4 P 2 S 6 crystal features large birefringence, high thermal stability (>750 °C), and a wide IR transmission range (0.4–18.2 μm).

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Cite This Study

Zhang et al. (2026) studied this question.

synapsesocial.com/papers/6a34de9d65a5b0777af2e003 https://doi.org/10.1039/d6qi00873a

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Optimal three-dimensional [Ag ₄ P ₂ S ₆ ]-framework assembly directed by a threefold roto-inversion axis for enhanced birefringence

Key Points

Implication

Abstract

Discussion

Cite This Study

Optimal three-dimensional [Ag ₄ P ₂ S ₆ ]-framework assembly directed by a threefold roto-inversion axis for enhanced birefringence

Key Points

Implication

Abstract

Discussion

Cite This Study

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