Experimental findings reveal magnetic properties of apatite crystals influenced by dioxocobaltate(II) anions, suggesting potential structural modifications.
values correspond to certain Co-O distances in the spin-only state. The distances follow a qualitative relation with estimated Coulomb forces acting between ions in the host compound. These findings suggest that to convert the dioxocobaltate(II) anion into the desired non-Aufbau state, one must construct a host apatite crystal from ions with lower charges and larger sizes.
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Sharifullin et al. (2026) studied this question.
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