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July 13, 2026Small

Engineered Framework Photocatalysts for Green H 2 O 2 Synthesis: Overcoming Fundamental Barriers With MOFs, COFs, and HOFs

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Authors

ABAkash BalakrishnanNRNatarajan RajamohanVSVishnuprasad Selvaraj

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Overview

Review analyzes framework-based photocatalysts for hydrogen peroxide production, highlighting challenges and scalability.

Key Points

  • This review aims to analyze the mechanisms behind framework-based photocatalysts for hydrogen peroxide synthesis and address associated challenges.
  • Unified analysis of photocatalysts using metal-organic frameworks, covalent organic frameworks, and hydrogen-bonded organic frameworks.
  • Discussion on framework architecture, defect engineering, and active-site coordination methods.
  • Critical evaluation of light harvesting, charge separation, and oxygen transport metrics.
  • Identified fundamental barriers to photocatalytic performance, such as rapid charge recombination and limited oxygen activation.
  • Highlighted benchmarking metrics, including apparent quantum yield and solar-to-chemical conversion efficiency.
  • Outlined strategies for improving scalability and effectiveness in real-world hydrogen peroxide production systems.

Cite This Study

Balakrishnan et al. (2026) studied this question.

synapsesocial.com/papers/6a548219475c38bf615a5ae0https://doi.org/10.1002/smll.74552
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