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July 15, 2026Advanced ScienceOpen Access

Synergy of Pd Clusters and TiO 2 101 for Photocatalytic Nonoxidative Coupling of Methane

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Authors

JYJie YangATAnnika S. TangJTJunwang Tang

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Overview

Randomized trial demonstrates high C2H6 production from methane, indicating improved catalytic stability.

Key Points

  • To enhance the photocatalytic nonoxidative coupling of methane into C2 hydrocarbons by utilizing a TiO2 photocatalyst with Pd clusters.
  • Developed a {101} facet-exposed TiO2 photocatalyst decorated with Pd single atoms and clusters.
  • Tested performance by measuring C2H6 production rate in a flow reactor at room temperature.
  • Evaluated the catalyst's stability over a 30-hour period.
  • Achieved a C2H6 production rate of 600 µmol·h−1·g−1 with nearly 100% selectivity.
  • Maintained stable performance over 30 hours with minimal degradation.
  • Demonstrated effective interfacial charge transfer and prevention of overoxidation.

Cite This Study

Yang et al. (2026) studied this question.

synapsesocial.com/papers/6a57229088b21df87547f975https://doi.org/10.1002/advs.202524322
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Also Consider

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  1. 1Unusual facet and co-catalyst effects in TiO2-based photocatalytic coupling of methane2024 · 106 citations
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  4. 4Precisely Modulating the Interfacial Oxygen Radicals for Selective Photocatalytic Methane Partial Oxidation to Methanol2026
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