Decoupling Thermodynamic Dilemma in the Crystallization of Cs ₃ BiSbBr ₉ Bimetallic Perovskites for Photocatalytic HBr Splitting

Xinghao Peng; Mingjie Li; Zimu Zhang; Yuru Zeng; Wei Fu; Leping Tang; Yuxuan Gong; Yufeng Zhu; Maosen Liu; Fang Lan; Hongyu Wu; Jiajie Wang; Chenghao Duan

doi:10.1021/acs.inorgchem.6c02233

July 15, 2026Inorganic Chemistry

Decoupling Thermodynamic Dilemma in the Crystallization of Cs ₃ BiSbBr ₉ Bimetallic Perovskites for Photocatalytic HBr Splitting

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Key Points

The primary objective is to establish a thermodynamic framework for the design of bimetallic perovskites that efficiently convert solar energy into chemical products.
Developed a thermodynamic paradigm for multicomponent perovskites.
Focused on the engineering challenges of crystallization and its impact on efficiency.
Explored the dual-product output in photocatalytic reactions.
Identified key thermodynamic factors influencing perovskite crystallization.
Demonstrated enhanced photocatalytic performance for HBr splitting with engineered perovskites.

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Implication

This work establishes thermodynamic principles for enhancing dual-product photocatalytic conversion in bimetallic perovskites.

Abstract

. This work establishes a thermodynamic paradigm for precisely engineering multicomponent perovskites toward dual-product solar-to-chemical conversion.

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Peng et al. (2026) studied this question.

synapsesocial.com/papers/6a59c664a58755010b471870 https://doi.org/10.1021/acs.inorgchem.6c02233

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Decoupling Thermodynamic Dilemma in the Crystallization of Cs ₃ BiSbBr ₉ Bimetallic Perovskites for Photocatalytic HBr Splitting

Key Points

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Implication

Abstract

Discussion

Cite This Study

Decoupling Thermodynamic Dilemma in the Crystallization of Cs ₃ BiSbBr ₉ Bimetallic Perovskites for Photocatalytic HBr Splitting

Key Points

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Implication

Abstract

Discussion

Cite This Study

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