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• Comprehensive description of activation and conversion techniques for hydrogen production from the reaction between aluminum powders and water. • Critical analysis of advantages and disadvantages of different aluminum powder-based methodologies for hydrogen generation. • Evaluation of high-pressure and high-temperature steam oxidation as a promising technique for efficient hydrogen production. • Investigation of the parameters and conditions influencing hydrogen yield in the ball milling activation process. This article presents a comparison of the various methodologies reported in the literature to generate hydrogen through the reaction between aluminum powders and water. This reaction, however, is hindered by the surface oxide layer, which prevents direct contact between pure aluminum and water. The low cost of aluminum, its infinite recyclability, and the potential to carry out the reaction in an environmentally sustainable manner make it a promising material for hydrogen production. Given the critical need to address the limitations of hydrogen storage and transportation, as well as to accelerate the adoption of hydrogen as an energy carrier for the energy transition, this comparison focuses on the two most environmentally promising methodologies: ball milling and steam oxidation methodologies.
Musicco et al. (Fri,) studied this question.