The ruthenium complex (IMesH 2 )(Cl) 2 (C 5 H 5 N) 2 Ru CHPh [IMesH 2 = 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene] ( 3 ) was prepared by the reaction of (IMesH 2 )(PCy 3 )(Cl) 2 Ru CHPh ( 2 ) with an excess of pyridine. Complex 3 contains substitutionally labile pyridine and chloride ligands and serves as a versatile starting material for the synthesis of new ruthenium benzylidenes.
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Sanford et al. (2001) studied this question.
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