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Emerging contaminants, notably antibiotics, pose significant risks to aquatic ecosystems and human health due to their persistence and potential to induce antibiotic resistance. An electro-Fenton (EF) process, utilizing in situ generated hydrogen peroxide (H 2 O 2 ), offers effective pollutant degradation. While current electrocatalysts often suffer from low H 2 O 2 selectivity, single-atom catalysts (SACs) have demonstrated superior activity and selectivity. However, their application is limited by poor acidic stability, particularly with nitrogen-coordinated site deactivation under strong oxidation conditions. Herein, a nitrogen-free cobalt single-atom catalyst (BP–Co) was synthesized on defect-rich carbon via ball milling-pyrolysis. BP–Co demonstrates 80% Faradaic efficiency and 10.5 mg cm –2 h –1 H 2 O 2 yield in acidic media. Both experimental and computational results demonstrate that the presence of surface epoxy groups improves interfacial wettability and electronically tailors the Co–C active sites, thus facilitating *OOH desorption and promoting H 2 O 2 generation. In EF applications, BP–Co achieves 100% removal of thiamphenicol (TAP), 77.9% TOC mineralization, continuous Fe 2+ regeneration, and low energy consumption (0.093 kWh (g TOC) −1 ). Moreover, the toxicity of degradation byproducts was significantly reduced. The system performs well across various water matrices and effectively degrades multiple organic pollutants. This study presents a cost-effective, stable strategy for nitrogen-free SACs, advancing water treatment technologies.
Luo et al. (Mon,) studied this question.