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The first examples of through-space conjugated thermally activated delayed fluorescence (TADF) emitters based on a [2.2]paracyclophane (PCP) skeleton with stacked (coplanar) donor-acceptor groups have been synthesized. The optoelectronic properties are studied by the relative configuration, cis (pseudo-geminal) and trans (pseudo-para), of the donor and acceptor groups.
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Spuling et al. (2018) studied this question.
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