Demonstrates a new epoxidation method for creating cyano-substituted epoxides, highlighting versatility.
Herein, we disclose a visible-light-induced, iminyl-radical-triggered deconstructive epoxidation of allylic peroxides that enables facile access to distal cyano-substituted epoxides. The operationally simple and modular strategy allows the transformation of allylic peroxides and cycloketone oxime derivatives into functionalized epoxides with a broad substrate scope and functional-group tolerance.
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Liu et al. (2026) studied this question.
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