Interlinked Zn-O-C infinite secondary building units (SBUs) form the basis of the novel metal-organic frameworks (MOFs) [Zn3(OH2)(X)2]⋅4 DEF⋅2 H2O (MOF-69A: X=4,4′-biphenyldicarboxylate; MOF-69B: X=2,6-naphthalenedicarboxylate; DEF=N,N′-diethylformamide). The nature of the infinite SBUs results in frameworks (structure of MOF-69A depicted) wherein catenation is forbidden.
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Rosi et al. (2002) studied this question.
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