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January 1, 2017Dalton Transactions

The key role of the composition and structural features in fluoride ion conductivity in tysonite Ce 1−x Sr x F 3−x solid solutions

Belto Dieudonné Johann Chable Monique Body Christophe Legein Étienne Durand Fabrice Mauvy Sébastien Fourcade M. Leblanc V. Maisonneuve Alain Demourgues

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Abstract

Evolution with x of RT ionic conductivity of RE 1−x AE x F 3−x showing that Ce 1−x Sr x F 3−x is the best F ⁻ tysonite conductor is discussed.

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Cite This Study

Dieudonné et al. (2017) studied this question.

synapsesocial.com/papers/6a5df52d646f15684ebc3dd9 https://doi.org/10.1039/c6dt04714a

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Batteries based on fluoride shuttleOriginal Research · 2011 · 501 citations
2Solid Electrolytes for Fluoride Ion Batteries: Ionic Conductivity in Polycrystalline Tysonite-Type FluoridesOriginal Research · 2014 · 190 citations
3Anionic high-temperature conduction in single crystals of nonstoichiometric phases R1 − y M y F3 − y (R = La-Lu, M = Ca, Sr, Ba) with the tysonite (LaF3) structureOriginal Research · 2007 · 24 citations
4Nonstoichiometric fluorides—Solid electrolytes for electrochemical devices: A reviewReview · 2007 · 146 citations
5Optimization of single crystals of solid electrolytes with tysonite-type structure (LaF3) for conductivity at 293 K: 2. Nonstoichiometric phases R 1−y M y F3−y (R = La-Lu, Y; M = Sr, Ba)Original Research · 2015 · 38 citations

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Fluoride solid electrolytes2009
Fluoride solid electrolytes: investigation of the tysonite-type solid solutions La <sub>1−x</sub> Ba <sub>x</sub> F <sub>3−x</sub> (x < 0.15)2015
Exploring the Sm1–xCaxF3–x Tysonite Solid Solution as a Solid-State Electrolyte: Relationships between Structural Features and F– Ionic Conductivity2015

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