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Demonstrates solvent effects on chirality-switchable luminescence in polymers, suggesting new material applications.
Poly(quinoxaline-2,3-diyl)s containing (S)-2-methylbutoxy side chains were found to exhibit blue circularly polarized luminescence (CPL). The handedness of the CPL could be switched by a solvent-dependent helix inversion of the polymer backbone between chloroform (M-helical structure) and 1,1,1-trichloroethane (P-helical structure).
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Nagata et al. (2014) studied this question.
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