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The synthesis of a hexa-peri-hexabenzocoronene (HBC) with a central borazine core is described. The solid-state structure of this BN-doped HBC (BN-HBC) is isotypic with that of the parent HBC. Scanning tunneling microscopy shows that BN-HBC lies flat on Au(111) in a two-dimensional pattern.
Krieg et al. (Tue,) studied this question.