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Reveals successful copolymerization of epoxides with CO2, indicating a new material formation.
Iron-corrole complexes were found to copolymerize epoxides with CO2. The first iron-catalyzed propylene oxide/CO2 copolymerization has been accomplished. Moreover, the glycidyl phenyl ether (GPE)/CO2 copolymerization with this catalyst provided a crystalline material as a result of the isotactic poly(GPE) moiety.
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Nakano et al. (2013) studied this question.
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