Macroscopic P3HT spherulitic crystals are grown in 25-nm-thick films via precise control of solvent swelling during polymer crystallization, which allow placement of transistor channels within single oriented crystal domains.Charge-transport anisotropy in the b–c (π-stacking & main chain) plane and the role of order–disorder grain boundaries are reported.
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Crossland et al. (2012) studied this question.
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