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Explores nucleophilic addition outcomes in boron cluster anions, suggesting effective synthetic pathways.
The processes of nucleophilic addition of acetylacetone as a C-nucleophile to multiple bonds of nitrile derivatives of boron cluster anions have been studied in this work. The structures of the products have been established by multinuclear NMR spectroscopy, ESI-mass spectrometry, and IR spectroscopy. The structure of compound (NBu4)[2-B10H9NH=C(C2H5)C(C(OH)CH3)C(O)CH3] has been established by single crystal X-ray analysis.
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Nelyubin et al. (2024) studied this question.
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