February 25, 2005Journal of the American Chemical Society538 citations

Highly Efficient Copper-Catalyzed Nitro-Mannich Type Reaction: Cross-Dehydrogenative-Coupling between sp3 C−H Bond and sp3 C−H Bond

ZLZhiping LiChongqing University of Posts and Telecommunications CLChao‐Jun LiUniversity of Notre Dame

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Abstract

A novel C-C bond formation method was developed via the cross-dehydrogenative-coupling (CDC) reaction catalyzed by using copper bromide in the presence of an oxidizing reagent, tert-BuOOH. The CDC reaction provides a simple and efficient catalytic method to construct beta-nitroamine via the reaction between sp3 C-H and sp3 C-H bonds.

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synapsesocial.com/papers/6a615a938791c6ab1cd0866e https://doi.org/https://doi.org/10.1021/ja050058j

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