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January 1, 2017Organic Chemistry Frontiers

Methodology and applications of the hexadehydro-Diels–Alder (HDDA) reaction

Oliver Diamond Todd B. Marder

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Abstract

Hexadehydro-Diels–Alder (HDDA) reactions between alkynes and 1,3-diynes readily generate highly reactive and synthetically useful arynes.

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Diamond et al. (2017) studied this question.

synapsesocial.com/papers/6a61a0127c867c6ae43f7232 https://doi.org/10.1039/c7qo00071e

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1The Diels-Alder Reaction in Total SynthesisReview · 2002 · 1,840 citations
2Reactions of aromatic compounds at high temperaturesOriginal Research · 1969 · 46 citations
3New Thermal Routes to ortho-BenzyneOriginal Research · 2010 · 32 citations
4Thermolysis of 1,3,8-Nonatriyne: Evidence for Intramolecular [2 + 4] Cycloaromatization to a Benzyne IntermediateOriginal Research · 1997 · 150 citations
5Synthesis and Properties of Functionalized [6] Helicenes by the Thermal Domino Radical Cycloaromatization of Acyclic PolyynesOriginal Research · 2001 · 14 citations

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