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December 1, 2001Polycyclic aromatic compounds

Synthesis and Properties of Functionalized [6] Helicenes by the Thermal Domino Radical Cycloaromatization of Acyclic Polyynes

Kazuhiro Miyawaki Tomikazu Kawano I. Ueda

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Abstract

Non-conjugated aromatic hexaynes and heptaynes undergo thermal domino radical cycloaromatization under mild conditions to yield indenol ring-fused fluoranthene and indenol ring-fused benzo[a]rubicene skeletons with helicity. The structure and thermal racemization of [6]helicene derivatives (12 and 13) are also described.

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Miyawaki et al. (2001) studied this question.

synapsesocial.com/papers/6a9377e8e22763ff8aa0ae84 https://doi.org/10.1080/10406630008034728

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