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The structure of sulfur-poly(acrylonitrile)-based Li-sulfur batteries is elucidated and correlated with the electrochemical performance of such devices. Apart from the poly(acrylonitrile)-derived backbone, thioamide as well as poly(sulfide) structures are proposed. Furthermore, the intermediary formation of S 8 during cycling and the role of the electrolyte in its reintegration during charging into are addressed. In summary, a comprehensive picture of the chemistry and electrochemistry of Li-sulfur batteries is presented.
Fanous et al. (Thu,) studied this question.