August 6, 2021Journal of the American Chemical Society119 citationsOpen Access

Catalytic Hydrodefluorination via Oxidative Addition, Ligand Metathesis, and Reductive Elimination at Bi(I)/Bi(III) Centers

YPYue Pang MLMarkus Leutzsch NNNils Nöthling

Key Points

Key points are not available for this paper at this time.

Abstract

)-H bond while regenerating the propagating Phebox-Bi(I). This protocol represents a distinct catalytic example where a main-group center performs three elementary organometallic steps in a low-valent redox manifold.

Demander à l'IA

Bookmark

View Full Paper

Cite This Study

Pang et al. (Fri,) studied this question.

synapsesocial.com/papers/6a61a7057c867c6ae43f7523 https://doi.org/https://doi.org/10.1021/jacs.1c06735

Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1The organometallic chemistry of the transition metals2001 · 1,733 citations
2Organometallic Fluorine Chemistry2015 · 45 citations
3Recycling the Waste: The Development of a Catalytic Wittig Reaction2009 · 319 citations
4Selectively catalytic hydrodefluorination of perfluoroarenes by Co(PMe3)4 with sodium formate as reducing agent and mechanism study2013 · 39 citations
5Frontiers in molecular p-block chemistry: From structure to reactivity2019 · 308 citations

Demander à l'IA

Bookmark

View Full Paper