We calculate exactly functional determinants for quantum oscillations about periodic instantons with a nontrivial value of the Polyakov line at spatial infinity. Hence, we find the weight or the probability with which calorons with nontrivial holonomy occur in the Yang-Mills partition function. The weight depends on the value of the holonomy, the temperature, ΛQCD, and the separation between the BPS monopoles (or dyons) that constitute the periodic instanton. At large separation between constituent dyons, the quantum measure factorizes into a product of individual dyon measures, times a definite interaction energy. We present an argument that at temperatures below a critical one related to ΛQCD, trivial holonomy is unstable, and that calorons ``ionize'' into separate dyons.
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Diakonov et al. (2004) studied this question.
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