Consolidation of Tantalum Powders by Spark Plasma Sintering: Densification, Wear and Corrosion Behavior

Tantalum (Ta) is an excellent alternative for structural orthopedic implants because of its high biocompatibility and chemical stability, but its melting point of 3020 °C severely complicates conventional casting. To address this, the study evaluates spark plasma sintering (SPS) to consolidate pure Ta powders at 1450 °C and 50 MPa and analyzes the impact of heating rates (50–200 °C/min) on microstructural, mechanical, wear, and corrosion properties. Results indicate that heating rate dictates final densification: a 50 °C/min rate achieved 98.59% relative density, whereas 200 °C/min yielded only 82.28% due to reduced thermal exposure. Sintering involved dislocation creep and viscous flow mechanisms, with X-ray diffraction confirming a stable α-Ta matrix across all samples. Mechanically, the 50 °C/min samples achieved a maximum microhardness of 285 HV, whereas higher porosity at 200 °C/min reduced hardness by 27.8%. Wear testing showed a two-stage friction evolution: an initial Ta2O5 solid-lubricating effect, followed by predominant abrasion and adhesion, with stable wear rates (3.2 to 3.6 × 10−3 mm3/N·m) for dense specimens. Finally, tests in simulated body fluid confirmed spontaneous self-passivation. However, the corrosion rate increased with heating rates, indicating that the resulting porosity adversely affects the material’s surface response.