Photoconductivity of Self-Assembled Porphyrin Nanorods

The photoconductivity of nanorods self-assembled from meso-tetrakis(4-sulfonatophenyl)porphine is described. The nanorods are insulating in the dark. Upon illumination with 488 nm light, the nanorods become photoconductive, exhibiting a rapid turn on/off (<100 ms) of the current when the light is turned on/off. This photoconductivity grows over hundreds of seconds with light exposure and decays slowly when the light is off. The nanorods can be trained via an applied bias to exhibit a short-circuit photocurrent (with corresponding open-circuit photovoltage) that flows in the direction opposite that of the training bias. A qualitative model is proposed, in which conduction occurs through the tightly coupled LUMOs of close-packed porphyrin molecules.