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The geminal chelate bis‐borylalkanes 4 and 5 featuring strongly electrophilic B(C 6 F 5 ) 2 and B(C 6 F 5 ) groups, respectively, serve as efficient catalysts for the borylation of arenes and heteroarenes. The borylation reactions proceed under mild conditions with liberation of dihydrogen.
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Liu et al. (2017) studied this question.
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