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Abstract The assessment of gas diffusion in water-saturated rocks is essential for quantifying gas loss and determining the amount of gas that could trigger abiotic and biotic processes, potentially altering fluid and rock properties. Additionally, estimating diffusion coefficients is critical for evaluating the balance between hydrogen generation and dissipation in radioactive waste repositories. This investigation involved experimental determination of diffusion coefficients for various gases both in water and in water-saturated Bentheim, Oberkirchner, Grey Weser, and Red Weser sandstones. Experimental conditions included pressures ranging from 0.2 to 1.0 MPa, consistently maintained at a temperature of 35 °C. The diffusion coefficients of hydrogen, helium, and methane in water were determined to be 6.7·10 –9 , 9.6·10 –9 , and 2.8·10 –9 m 2 /s, respectively, consistent with literature values obtained through gas concentration measurements without pressure gradients. However, the diffusivity of carbon dioxide and argon in water was measured at 10.9·10 –9 and 44.6·10 –9 m 2 /s, significantly exceeding their corresponding literature values by an order of magnitude. This discrepancy is attributed to the significant solubility of these gases in water, resulting in density-driven convection as the primary transport mechanism. Furthermore, the effective diffusion coefficients for hydrogen within the analyzed rock specimens varied from 0.8·10 –9 to 2.9·10 –9 m 2 /s, which are higher than those for methane and carbon dioxide, both ranging from 0.3·10 –9 to 0.9·10 –9 m 2 /s. This yielded diffusive tortuosity values ranging from 2.6 to 8.2. The observed effective diffusivity values were positively correlated with porosity, permeability, and mean pore size, while exhibiting a negative correlation with tortuosity. Given that the gas–liquid mass transfer coefficient is directly proportional to the effective gas diffusivity in water, the determined values for H 2 are essential for studying the impact of pore characteristics on microbial activity.
Khajooie et al. (Wed,) studied this question.