Computational and Experimental Investigation of Chiral and Achiral Two‐Dimensional Organic Lead Bromide Perovskites: Octahedral Distortions and Electronic and Optical Properties

A computational investigation is presented, in conjunction with synthesis and experimental characterization, into the structural, electronic, and optical properties of layered two‐dimensional organic lead bromide perovskites. Materials based on the chiral (R/S)‐4‐fluoro‐α‐methylbenzylammonium (R/S‐FMBA), which have been shown to lead to bright room‐temperature circularly polarized luminescence, are contrasted with the similar achiral 4‐fluorobenzylammonium (FBA). Using density functional theory (DFT) with van der Waals (vdW) corrections, relaxed structures (compared with X‐ray diffraction, XRD) and optical absorption spectra (compared with experiments) are studied, as well as band structure and orbital character of transitions. A Python code is developed and provided to calculate octahedral distortions and compare DFT and XRD results, finding that vdW corrections are important for accuracy and that DFT overestimates octahedral tilt angles. (FMBA) 2 PbBr 4 shows among the largest tilt angle differences (often termed ) reported, 14°–15°, indicating strong inversion symmetry‐breaking, which enables its chiral emission. A large resulting Dresselhaus spin‐splitting effect is found. The lowest‐energy optical transitions involve the perovskite only and are polarized within the layer. This work furthers understanding of structure‐property relations with applications to optoelectronics and spintronics.