Versatile Anion–π Interactions between Halides and a Conformationally Rigid Bis(tetraoxacalix[2]arene[2]triazine) Cage and Their Directing Effect on Molecular Assembly

Interactive halides: Bis(tetraoxacalix[2]arene[2]triazine), a conformationally rigid cage molecule of three V-shaped electron-deficient clefts, forms 1:1 complexes with fluoride (361 M−1), chloride (146 M−1) and bromide (95 M−1) in acetonitrile. Different anion–π interactions along with multiple hydrogen bonding, halogen bonding and lone-pair-electrons–π interactions directed the formation of different molecular assemblies (an example is shown here). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.