December 5, 2008Journal of the American Chemical Society236 citations

Reversible, Metal-Free, Heterolytic Activation of H2 at Room Temperature

MUMatthias S. Ullrich ALAlan J. Lough DSDouglas W. Stephan

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Abstract

The combination of the borane B(p-C(6)F(4)H)(3) and (o-C(6)H(4)Me)(3)P activates H(2) to give (o-C(6)H(4)Me)(3)PHHB(p-C(6)F(4)H)(3). This salt when placed under vacuum releases H(2) at room temperature.

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Ullrich et al. (Fri,) studied this question.

synapsesocial.com/papers/6a62a303fe5b6bd6fe96b263 https://doi.org/https://doi.org/10.1021/ja808506t

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