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Double impact: The title method gives aryl vinyl ethers in high yields, short reaction times, Z-stereospecificity, and good regioselectivities. Insights into the reaction mechanism highlight the role of Au (NHC) 2 (μ-OH) BF4 (NHC=N-heterocyclic carbene) as both a Lewis acid, Au (NHC) BF4, and a Brønsted base, Au (NHC) (OH), thereby generating a synergistic effect between the two gold moieties.
Oonishi et al. (Mon,) studied this question.
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